Thermodynamic Model Prediction of Metal Removal during "Hydrogen Annealing" of Si Wafers

© 1995 ECS - The Electrochemical Society
, , Citation C. R. Helms 1995 J. Electrochem. Soc. 142 L125 DOI 10.1149/1.2050108

1945-7111/142/8/L125

Abstract

We report on the development and application of a quasi‐chemical thermodynamic model of metal evaporation (desorption) from Si surfaces during high temperature processing, specifically a high temperature wafer process referred to as hydrogen annealing (or baking). We show that significant depletion of many metals can be expected during such a process. This is an additional benefit of hydrogen annealing, providing another mechanism for improved defect levels in MOS gate oxides grown on hydrogen annealed wafers.

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10.1149/1.2050108