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Erschienen in: Urolithiasis 5/2010

01.10.2010 | Original Paper

Infrared and Raman studies on renal stones: the use of second derivative infrared spectra

verfasst von: José Rodolfo Guerra-López, Jorge Alberto Güida, Carlos Omar Della Védova

Erschienen in: Urolithiasis | Ausgabe 5/2010

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Abstract

Urolithiasis is a very frequent illness found in Argentina; however, stone analysis is not routinely performed. In this work, 86 renal calculi (from cities of Luján and San Antonio de Areco, State of Buenos Aires, Argentina) have been analyzed by infrared and Raman spectroscopies, and the results correlated with the main possible pathological conditions. Calcium oxalate monohydrate (whewellite) and mixtures of calcium oxalate monohydrate and carbonate apatite were the most frequent compounds found in our samples. In order to improve the identification of different phases present in calculi [particularly whewellite and weddellite (calcium oxalate dihydrate)], the second derivative spectra were used. The FTIR spectroscopy together with the second derivative analysis provides the urologist with a good method for calculi component determinations.
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Literatur
2.
Zurück zum Zitat Hesse A, Sanders G (eds) (1988) Atlas of infrared spectra for the analysis of urinary concrements. Georg Thieme Verlag, New York Hesse A, Sanders G (eds) (1988) Atlas of infrared spectra for the analysis of urinary concrements. Georg Thieme Verlag, New York
3.
Zurück zum Zitat Bazin D, Chevallier P, Matzen G, Jungers P, Daudon M (2007) Heavy elements in urinary stones. Urol Res 35:179–184CrossRefPubMed Bazin D, Chevallier P, Matzen G, Jungers P, Daudon M (2007) Heavy elements in urinary stones. Urol Res 35:179–184CrossRefPubMed
4.
Zurück zum Zitat Abboud IA (2008) Concentration effect of trace metals in Jordanian patients of urinary calculi. Environ Geochem Health 30:11–20CrossRefPubMed Abboud IA (2008) Concentration effect of trace metals in Jordanian patients of urinary calculi. Environ Geochem Health 30:11–20CrossRefPubMed
5.
Zurück zum Zitat Vergauwe DAG, Verbeeck RMH, Oosterlinck W (1994) Analysis of urinary calculi. Acta Urol Belg 62:5–13PubMed Vergauwe DAG, Verbeeck RMH, Oosterlinck W (1994) Analysis of urinary calculi. Acta Urol Belg 62:5–13PubMed
6.
Zurück zum Zitat Ansari M, Gupta N, Hemal A et al (2005) Spectrum of stone composition: structural analysis of 1050 upper urinary tract calculi from northern India. Int J Urol 12:12–16CrossRefPubMed Ansari M, Gupta N, Hemal A et al (2005) Spectrum of stone composition: structural analysis of 1050 upper urinary tract calculi from northern India. Int J Urol 12:12–16CrossRefPubMed
7.
Zurück zum Zitat Aprien EL, Frondel C (1947) Studies in urolithiasis. I. The composition of urinary calculi. J Urol 57:949–994 Aprien EL, Frondel C (1947) Studies in urolithiasis. I. The composition of urinary calculi. J Urol 57:949–994
8.
Zurück zum Zitat Lonsadale K, Suttor DJ, Wooley SE (1968) Composition of urinary calculi by X-ray diffraction. Collected data from various localities. I. Norwich (England) and district. Br J Urol 40:33–36 Lonsadale K, Suttor DJ, Wooley SE (1968) Composition of urinary calculi by X-ray diffraction. Collected data from various localities. I. Norwich (England) and district. Br J Urol 40:33–36
9.
Zurück zum Zitat Suttor DJ (1971) Crystallographic studies on the formation of renal calculi. Proceeding of the Biochemical Society. Biochem J 122:6–7 Suttor DJ (1971) Crystallographic studies on the formation of renal calculi. Proceeding of the Biochemical Society. Biochem J 122:6–7
11.
Zurück zum Zitat Nalbandyan BV (2008) X-ray diffraction analysis of urinary calculi: need for heat treatment. Urol Res 36:247–249CrossRefPubMed Nalbandyan BV (2008) X-ray diffraction analysis of urinary calculi: need for heat treatment. Urol Res 36:247–249CrossRefPubMed
12.
Zurück zum Zitat Uldall A (1981) Analysis of urinary calculi; a quality control programme. Scand J Clin Lab Invest 41:339–345CrossRefPubMed Uldall A (1981) Analysis of urinary calculi; a quality control programme. Scand J Clin Lab Invest 41:339–345CrossRefPubMed
13.
Zurück zum Zitat Rebentisch G, Berg W (1989) Comparison of methods and guaranteeing quality of analyses of urinary calculi: 5th international ring test. Urol Int 44:298–302CrossRefPubMed Rebentisch G, Berg W (1989) Comparison of methods and guaranteeing quality of analyses of urinary calculi: 5th international ring test. Urol Int 44:298–302CrossRefPubMed
14.
Zurück zum Zitat Blijenbergh BG, Baadenhuysen H (1990) De resultaten van verschillende analysetechnieken met betrekking tot urinesteen onderzoek. Ned Tijdschr Geneeskd 134:1402–1404 Blijenbergh BG, Baadenhuysen H (1990) De resultaten van verschillende analysetechnieken met betrekking tot urinesteen onderzoek. Ned Tijdschr Geneeskd 134:1402–1404
15.
Zurück zum Zitat Paluszkiewicz C, Galka M, Kwiatek W, Parczewski A, Walas S (1997) Renal stone studies using vibrational spectroscopy and trace element analysis. Biospectroscopy 3:403–407CrossRef Paluszkiewicz C, Galka M, Kwiatek W, Parczewski A, Walas S (1997) Renal stone studies using vibrational spectroscopy and trace element analysis. Biospectroscopy 3:403–407CrossRef
16.
Zurück zum Zitat Safaa K, Khalil H, Mohamead AA (2007) Application of vibrational spectroscopy in identification of the composition of the urinary stones. J Appl Sci Res 5:387–391 Safaa K, Khalil H, Mohamead AA (2007) Application of vibrational spectroscopy in identification of the composition of the urinary stones. J Appl Sci Res 5:387–391
17.
Zurück zum Zitat Daudon M, Bader CA, Jungers P (1993) Urinary calculi: review of classification methods and correlations with etiology. Scanning Microsc 7:1081–1106PubMed Daudon M, Bader CA, Jungers P (1993) Urinary calculi: review of classification methods and correlations with etiology. Scanning Microsc 7:1081–1106PubMed
18.
Zurück zum Zitat Grases F, Costa-Bauza A, Ramis M, Montesinos V, Conte A (2002) Simple classification of renal calculi closely related to their micromorphology and etiology. Clin Chim Acta 322:29–36CrossRefPubMed Grases F, Costa-Bauza A, Ramis M, Montesinos V, Conte A (2002) Simple classification of renal calculi closely related to their micromorphology and etiology. Clin Chim Acta 322:29–36CrossRefPubMed
19.
Zurück zum Zitat Leung Y, Walters A, LeGeros RZ (1990) Second derivative infrared spectra of hydroxyapatite. Spectrochim Acta 46(10):1453–1459CrossRef Leung Y, Walters A, LeGeros RZ (1990) Second derivative infrared spectra of hydroxyapatite. Spectrochim Acta 46(10):1453–1459CrossRef
20.
Zurück zum Zitat Talsky G (1994) Derivative spectrophotometry. VCH Verlagsgesellschaft, mbH, Weinheim Talsky G (1994) Derivative spectrophotometry. VCH Verlagsgesellschaft, mbH, Weinheim
21.
Zurück zum Zitat Guerra-López J R (2005) Efecto de la presencia de cationes divalentes en la síntesis de hidroxiapatitas y compuestos relacionados. Modelo utilizado en el estudio del Tejido óseo. PhD thesis, Universidad Nacional de Luján, Lujan, Argentina Guerra-López J R (2005) Efecto de la presencia de cationes divalentes en la síntesis de hidroxiapatitas y compuestos relacionados. Modelo utilizado en el estudio del Tejido óseo. PhD thesis, Universidad Nacional de Luján, Lujan, Argentina
22.
Zurück zum Zitat Maddams WF, Tooke PB (1982) Quantitative conformational studies on poly(vinyl chloride. J Macromol Sci A17:951–968 Maddams WF, Tooke PB (1982) Quantitative conformational studies on poly(vinyl chloride. J Macromol Sci A17:951–968
23.
Zurück zum Zitat Kuzmanovski Igor, Trpkovska Mira, Sŏptrajanov Bojan (2005) Optimization of supervised self-organizing maps with genetic algorithms for classification of urinary calculi. J Mol Struct 744–747:833–838CrossRef Kuzmanovski Igor, Trpkovska Mira, Sŏptrajanov Bojan (2005) Optimization of supervised self-organizing maps with genetic algorithms for classification of urinary calculi. J Mol Struct 744–747:833–838CrossRef
24.
Zurück zum Zitat Kuzmanovski Igor, Zdravkovab Katerina, Trpkovska Mira (2006) Classification of urinary calculi using feed-forward neural networks. S Afr J Chem 59:12–16 Kuzmanovski Igor, Zdravkovab Katerina, Trpkovska Mira (2006) Classification of urinary calculi using feed-forward neural networks. S Afr J Chem 59:12–16
25.
Zurück zum Zitat Chevreau G, Troccaz J, Conort P, Renard-Penna R, Mallet A, Daudon M, Mozer P (2009) Estimation of urinary stone composition by automated processing of CT images. Urol Res 37:241–245CrossRefPubMed Chevreau G, Troccaz J, Conort P, Renard-Penna R, Mallet A, Daudon M, Mozer P (2009) Estimation of urinary stone composition by automated processing of CT images. Urol Res 37:241–245CrossRefPubMed
26.
Zurück zum Zitat Grases F, Millan A, Conte A (1990) Production of calcium oxalate monohydrate, dihydrate or trihydrate. A comparative study. Urol Res 18:17–20CrossRefPubMed Grases F, Millan A, Conte A (1990) Production of calcium oxalate monohydrate, dihydrate or trihydrate. A comparative study. Urol Res 18:17–20CrossRefPubMed
27.
Zurück zum Zitat Stavitzky A, Golay MJE (1964) Smoothing and differentiation of data by simplified least squares procedures. Anal Chem 36:1627–1639CrossRef Stavitzky A, Golay MJE (1964) Smoothing and differentiation of data by simplified least squares procedures. Anal Chem 36:1627–1639CrossRef
28.
Zurück zum Zitat Begun GM, Fletcher WH (1963) Vibrational spectra of aqueous oxalate ion. Spectrochim Acta 19:1343–1349CrossRef Begun GM, Fletcher WH (1963) Vibrational spectra of aqueous oxalate ion. Spectrochim Acta 19:1343–1349CrossRef
29.
Zurück zum Zitat Frost RL (2004) Raman spectroscopy of natural oxalates. Anal Chim Acta 517:207–214CrossRef Frost RL (2004) Raman spectroscopy of natural oxalates. Anal Chim Acta 517:207–214CrossRef
30.
Zurück zum Zitat Frost RL, Weier ML (2004) Thermal treatment of whewellite—a thermal analysis and Raman spectroscopic study. Thermochim Acta 409:79–85CrossRef Frost RL, Weier ML (2004) Thermal treatment of whewellite—a thermal analysis and Raman spectroscopic study. Thermochim Acta 409:79–85CrossRef
31.
Zurück zum Zitat Guerra-López J, Pomés R, Della Védova CO, Viña R, Punte G (2001) Influence of nickel on hydroxyapatite crystallization. J Raman Spectrosc 32:256–261CrossRef Guerra-López J, Pomés R, Della Védova CO, Viña R, Punte G (2001) Influence of nickel on hydroxyapatite crystallization. J Raman Spectrosc 32:256–261CrossRef
32.
Zurück zum Zitat Hesse A, Siener R (1997) Current aspect of epidemiology and nutrition in urinary stone disease. World J Urol 15:165–171CrossRefPubMed Hesse A, Siener R (1997) Current aspect of epidemiology and nutrition in urinary stone disease. World J Urol 15:165–171CrossRefPubMed
33.
Zurück zum Zitat Balla AA, Salah AM, Kambal A, Bongartz D, Hoppe B, Hesse A (1998) Mineral composition of renal stones from the Sudan. Urol Int 61:154–156CrossRefPubMed Balla AA, Salah AM, Kambal A, Bongartz D, Hoppe B, Hesse A (1998) Mineral composition of renal stones from the Sudan. Urol Int 61:154–156CrossRefPubMed
34.
Zurück zum Zitat Robert M, Boularan A, Delbos O, Guiter J, Descomps B (1998) Study of calcium oxalate crystalluria on renal and vesical urines in stone formers and normal subjects. Urol Int 60:41–46CrossRefPubMed Robert M, Boularan A, Delbos O, Guiter J, Descomps B (1998) Study of calcium oxalate crystalluria on renal and vesical urines in stone formers and normal subjects. Urol Int 60:41–46CrossRefPubMed
35.
Zurück zum Zitat Pak CY, Poindexter JR, Peterson RD, Heller HJ (2004) Biochemical and physicochemical presentations of patients with brushite stones. J Urol 171:1046–1049CrossRefPubMed Pak CY, Poindexter JR, Peterson RD, Heller HJ (2004) Biochemical and physicochemical presentations of patients with brushite stones. J Urol 171:1046–1049CrossRefPubMed
36.
Zurück zum Zitat Martínez Muñoz JM (2004) Litiasis renal Oxálica. Avances en la comprensión de su etiología y mejoras en la metodología analítica para su estudio. PhD thesis, Departamento de Química, Universidad Autónoma de Barcelona, España Martínez Muñoz JM (2004) Litiasis renal Oxálica. Avances en la comprensión de su etiología y mejoras en la metodología analítica para su estudio. PhD thesis, Departamento de Química, Universidad Autónoma de Barcelona, España
Metadaten
Titel
Infrared and Raman studies on renal stones: the use of second derivative infrared spectra
verfasst von
José Rodolfo Guerra-López
Jorge Alberto Güida
Carlos Omar Della Védova
Publikationsdatum
01.10.2010
Verlag
Springer-Verlag
Erschienen in
Urolithiasis / Ausgabe 5/2010
Print ISSN: 2194-7228
Elektronische ISSN: 2194-7236
DOI
https://doi.org/10.1007/s00240-010-0305-2

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